Usually you capture the workflows or "user journeys" so that you can build tests that mirror the reality of what people are doing. The problem is that even when you do that there will be variances in the "journey".
For example the user journey might be "Arrived at office, logs on to computer, makes coffee, returns to desk and starts work". Most users adhere, then you get the one that insists on buying coffee, arriving at the office then logging onto the computer, and the one that arrives at office, wanders about a bit, makes a coffee, remembers they are meant to be working and logs onto computer and the one that arrives at office, practices juggling, logs on, makes a coffee, starts work.
Woah! Juggling? No-one mentioned juggling? Why are you juggling? Are you meant to be juggling?
Can we address the juggling issue? Yes, the system supports juggling but we haven't tested that because no-one has mentioned the need to juggle?